This problem ...
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When I start purling, it goes well, then the yarn between the opposite end of circular needle, or the other needle, (I've tried both), gets longer and longer and hard to pull neatly.
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... has nothing to do with purling. It sounds like you're doing the backwards loop cast on and it's not a good one for lots of stitches on a circular, nor is it easy to knit or purl a stitch into it.. Try the knit or cable cast on and the purling will go a lot easier.